N-Benzotriazol-1-yl-methyl-1,2,3,4-tetrahydro-b-carboline
نویسندگان
چکیده
منابع مشابه
(1H-1,2,3-Benzotriazol-1-yl)methyl benzoate
In the title compound, C(14)H(11)N(3)O(2), the dihedral angle between the phenyl ring and the benzotriazole ring system is 76.80 (19)° and the mol-ecule has an L-shaped conformation. In the crystal, weak aromatic π-π stacking is observed, the closest centroid-centroid distance being 3.754 (2) Å.
متن کامل(1H-1,2,3-Benzotriazol-1-yl)methyl 2,2-dimethylpropanoate
In the title compound, C(12)H(15)N(3)O(2), the dihedral angle between the mean planes of the benzene and triazole rings is 0.331 (53) °. The side chain of the pivalate unit forms a dihedral angle of 69.04 (12)° with the benzotriazole unit. The ester group and two methyl groups of the pivalate unit are disordered with an occupancy ratio of 0.731 (3):0.269 (3). In the crystal, weak π-π stacking i...
متن کامل2-(1H-1,2,3-Benzotriazol-1-yl)-N′-cyclopentylideneacetohydrazide
The title compound, C(13)H(15)N(5)O, was synthesized by the reaction of 2-(1H-1,2,3-benzotriazol-1-yl)acetohydrazide with cyclo-penta-none. In the cyclopentane ring, two C atoms and their attached H atoms are disordered over two positions; the site occupancy factors are ca 0.63 and 0.37. In the crystal structure, mol-ecules are linked into infinite chains directed along the b axis by N-H⋯O hydr...
متن کامل2-(1H-1,2,3-Benzotriazol-1-yl)-N′-(2-chlorobenzylidene)acetohydrazide
In the title compound, C(15)H(12)ClN(5)O, the mean planes of the benzotriazole and chloro-phenyl fragments form a dihedral angle of 70.8 (1)°. In the crystal, mol-ecules are linked into infinite chains along the a axis by N-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯N hydrogen bonds further link these chains into layers parallel to the ab plane. The crystal studied was a racemic twin.
متن کاملMethyl 1-(7-acetamido-5,8-dimethoxyquinolin-2-yl)-4-methyl-β-carboline-3-carboxylate
The title compound, C(27)H(24)N(4)O(5), is an inter-mediate in the synthesis of lavendamycin via a ruthenium-catalysed [2 + 2 + 2] cyclo-addition. An intra-molecular hydrogen-bond bridge from the carboline to the quinoline stabilizes a highly planar geometry [maximum deviation = 0.065 (6) Å] for the two rigid units. This hydrogen-bond-stabilized coplanarity has a very close analogy in the struc...
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ژورنال
عنوان ژورنال: Molecules
سال: 2000
ISSN: 1420-3049
DOI: 10.3390/m182